A spectral line is a particular distinct frequency or narrow band of a frequency set. The resonance of this frequency occurs corresponding to a particular chemical shift. Theoretically, the frequency of a pure sine wave displays sharp spectral lines at the point of Larmor frequency. In reality, the spectral lines spread into a blurred peak, caused by field inhomogeneities and spin-spin effect.
Postprocessing of the spectrum to suppress baseline deviations from zero that may be superimposed on desired spectral lines. These deviations may be due either to various instrumental effects or to very broad spectral lines.
Convolution differentiation is a method of suppressing broad underlying spectral lines in order to emphasize narrower spectral lines. Strong smoothing of the spectrum (e.g., by severe negative exponential weighting of the time data) will suppress the narrow lines but minimally affect very broad ones; subtracting such a smoothed spectrum from the original will largely remove the contributions from the broad lines. This provides a means of baseline correction.
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Echo offset is the time setting of spinecho and gradientecho to be not coincident and to generate phase differences between different spectral line signals (e.g., water and fat). The echo offset is the product of the frequency line difference and the time difference (TD) in the echo times and is equal to the magnitude of the result of the phase difference between two spectral lines. Phases may not change linearly with echo offset time in the presence of a large field inhomogeneity. An echo offset excitationpulse sequence can be used in the magnetic field
mapping method, to generate maps from which the standard deviation of the phase difference can be calculated.
(FWHM) A commonly used measure of the width at half the maximum value of peaked functions such as spectral lines or slice profiles and important measure of the quality of an imaging device and its spatial resolution.
As the name states, the FWHM is measured by identifying the points on the signal curve, which are half the maximum value. The horizontal distance between these two points is called the FWHM. For a spectral line, this will be proportional to 1/T2.